Grand Anne

Anne Hathaway may have kicked off her career playing a teen princess, but the "Bride Wars" star has since become Hollywood royalty – she even nabbed an Oscar nomination for her role in the indie flick "Rachel Getting Married."

And when it comes to beauty, she's a pro at creating trendy looks that still seem classic.

With her major eyes and full lips, it's easy to see why ebony eyeliner and pinky-red lipstick have become this starlet's favorite co-stars.

But that doesn't mean she doesn't love to switch it up. Nude lips are always a chic alternative to a pronounced pout. She's channeling Edie Sedgwick with this mod look.

Anne goes for vintage Hollywood glam with classic crimson lips and sunset-hued shadows. Va-va-voom.

Coppery-brown shadow – layered over black liner – lends the fashion-savvy star a casually cool vibe. "Get Smart?" She's already there.

This "Bride War"-rior knows that brown-eyed girls benefit from all shades of chocolate-y shadows, including soft taupes and barely-there beiges.

For maximum drama on the red carpet, the gamine starlet flaunts fire engine-red lips, smoky eyes and perfectly arched eyebrows. Perhaps she's still a princess at heart?

For more beauty content brought to you by CoverGirl, click here.